Product ID:OIL BLACK, 62497
MSDS Date:05/07/1996
FSC:8010
NIIN:00N081083
MSDS Number: CFWLK

RAABE CORP

N92 W14701 ANTHONY AVE
MENOMONEE FALLS, WI 53052-1090
US

Emergency Phone: 800-424-9300(CHEMTREC)

Info Phone: 800-966-7580

Preparer: BOB BATH

Cage: 0A3L4

RAABE CORPORATION THE PRECISION COLOR COMPANY

1090 MENOMONEE FALLS, WI 53051-1630 US

Telephone: 414-255-9500/800-966-7580

Cage: 0A3L4

ETHANOL, 2-BUTOXY-; (2-BUTOXYETHANOL)

CAS: 111-76-2

RTECS: KJ8575000

Fraction By Weight: <2%

OSHA PEL 50 PPM, S

ACGIH TLV: 25 PPM, S

2-BUTANONE; (METHYL ETHYL KETONE) (MEK) (SARA 313) (CERCLA)

CAS: 78-93-3

RTECS: EL6475000

Fraction By Weight: <17%

OSHA PEL 200 PPM

ACGIH TLV: 200 PPM;300 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER; (PROPYLENE

CAS: 108-65-6

RTECS: AI8925000

Fraction By Weight: <28%

OSHA PEL N/K

ACGIH TLV: N/K

BUTYL BENZYL PHTHALATE (SARA 313) (CERCLA)

CAS: 85-68-7

RTECS: TH9990000

Fraction By Weight: <5%

OSHA PEL 5 MG/M3 (MFR)

ACGIH TLV: 5 MG/M3 (MFR)

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

TOLUENE (SARA 313) (CERCLA)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: <34%

OSHA PEL 200 PPM

ACGIH TLV: 50 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ISOPROPYL ALCOHOL (SARA 313)

CAS: 67-63-0

RTECS: NT8050000

Fraction By Weight: <2%

OSHA PEL 400 PPM

ACGIH TLV: 400 PPM;500 STEL

ACRYLIC POLYMER

CAS: 25068-63-7

Fraction By Weight: <30%

OSHA PEL N/K

ACGIH TLV: N/K

ALUMINUM; (ALUMINUM FLAKE) (SARA 313)

CAS: 7429-90-5

RTECS: BD0330000

Fraction By Weight: <4%

OSHA PEL 15 MG/M3 DUST

ACGIH TLV: 10 MG/M3 DUST

NITROCELLULOSE

CAS: 9004-70-0

RTECS: QW0970000

Fraction By Weight: <4%

OSHA PEL N/K

ACGIH TLV: N/K

AMORPHOUS SILICA GEL; (AMORPHOUS PRECIPITATED SILICA)

CAS: 112926-00-8

Fraction By Weight: <5%

OSHA PEL N/K

ACGIH TLV: 10 MG/M3 (MFR)

STODDARD SOLVENT; (MINERAL SPIRITS)

CAS: 8052-41-3

RTECS: WJ8925000

Fraction By Weight: <4%

OSHA PEL 500 PPM

ACGIH TLV: 100 PPM

TRIMETHYLBENZENE; (MIXED ISOMERS)

CAS: 25551-13-7

RTECS: DC3220000

Fraction By Weight: <5%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM

BENZENE, 1,2,4-TRIMETHYL-; (1,2,4-TRIMETHYLBENZENE) (SARA

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: <4%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM

XYLENE (SARA 313) (CERCLA)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: <4%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM;150 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

PIGMENTS; (ORGANIC & INORGANIC PIGMENTS)

Fraction By Weight: <19%

OSHA PEL N/K

ACGIH TLV: N/K

FLAKE CAN ALSO REACT W/SOME ACIDS, CAUSTIC

RTECS: 9999999ZZ

SILICOSIS. INTENTIONAL MISUSE BY DELIB CONC

RTECS: 9999999ZZ

MOD TOX. MAY CAUSE STOM DISCOMFORT, NAUS,

RTECS: 9999999ZZ

TOLUENE APPEARS ON NAVY

RTECS: 9999999ZZ

APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST

RTECS: 9999999ZZ

CLEARLY DEMONSTRATED DOSE-RELATED ADVERSE EFTS ON

RTECS: 9999999ZZ

W/ADMIN OF 2-BUTOXYETHANOL. (EXTRACTED FROM DHHS

RTECS: 9999999ZZ

DMG, EYE, BLOOD, LUNG, LIVER, SPLEEN, BRAIN & REPRO

RTECS: 9999999ZZ

RPTS HAVE ASSOC RPTD & PRLNG OVEREXP TO SOLVS W/PERM

RTECS: 9999999ZZ

HIGH

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYE CONT:MAY CAUSE SEV
IRRIT/CORNEAL INJURY. SKIN CONT:RPTD & PRLNG CONT MAY CAUSE
ALLERGIC DERM, IRRIT; OR MAY BE ABSORBED. EXCESS EXPOS MAY CAUSE
HEMOLYSIS (RED BLOOD CELL DMG) WHICH CAN IMPAI R BLOOD'S ABILITY TO
TRANPORT OXYG. INHAL:EXPOS TO HIGH CONCS OF VAPS MAY CAUSE DIZZ,
BRTHG DFCLTY, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:HDCHS/RESP IRRIT. EXTREMELY HIGH CONCS
MAY CAUSE DROW, STAG, CONFUSN, UNCON, COMA/DEATH. EXCESS INHAL OF
VAPS CAN CAUSE NASAL & RESP IRRIT. LIQ/VAP MAY BE IRRIT TO SKIN,
EYES, THROAT/LUNGS. P RLNG INHAL OF DUSTS CNTNG FREE SILICA MAY
RSLT IN DEVEL OF DISABLING PULM FIBROSIS (LUNG DISEASE) KNOWN AS
(ING 17)
Medical Cond Aggravated by Exposure:MATERIAL MAY AGGRAVATE AN EXISTING
DERMATITIS.

First Aid:EYES:FLUSH W/LG QTYS OF WATER FOR AT LST 15 MINS. SKIN:WASH
THORO W/SOAP & WATER & SEEK MED ATTN. REMOVE & LAUNDER CONTAM CLTHG
BEFORE REUSE. INHAL:MOVE PERS TO FRESH AIR. IF BRTHG STOPS, APPLY
ARTF R ESP & SEEK MED ATTN. INGEST:SINCE PROD MAY CNTN MATLS WHICH
CAN CAUSE LUNG DMG IF ASPIR INTO LUNGS, DECISION OF WHETHER TO
INDUCE VOMIT/NOT MUST BE MADE BY MD AFTER CAREFUL CONSIDERATION OF
ALL MATLS.

Flash Point Method:TCC
Flash Point:28.0F,-2.2C
Lower Limits:0.3%
Upper Limits:13.1%
Extinguishing Media:DRY CHEMICAL, CO*2 OR FOAM.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY SHOULD NOT BE USED EXCEPT TO KEEP DOWN VAPS/COOL CLSD
CNTNRS TO PVNT BUILD-UP OF PRESS. IF (SUPDAT)
Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM
HEAT, SPKS & OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO
EXTREME HEAT. PROD VAPS ARE HVR/AIR & MAY TRAVEL A(SUPDAT)

Spill Release Procedures:REMOVE ALL SOURCES OF IGNIT. AVOID HEAT,
SPARKS, FLAMES & ANYTHING WHICH COULD CAUSE FIRE. VENTILATE AREA OF
SPILL & ADJACENT LOW LYING AREAS. AVOID BREATHING SOLVENT VAPORS.
REMOVE W/INERT ABSORBENT MATERIALS & NON-SPARKING TOOLS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:SMOKE IN DESIGNATED AREAS ONLY. STORE
IN A COOL, DRY AREA W/VENTILATION SUITABLE FOR STORING INGREDIENTS.
DO NOT STORE AT TEMPERATURES >120F.
Other Precautions:STORE IN COOL PLACE AWAY FROM DIRECT SUNLIGHT/ANY
SOURCE OF IGNIT. MAY BE FATAL IF SWALLOWED. HARMFUL IF
INHALED/ABSORBED THRU SKIN. CAUSES EYE/SKIN IRRIT. VAPS IRRIT TO
EYES & RESP TRACT. FLAMM LIQ & VAP. VAPS MAY CAUSE FLASH
FIRE/EXPLO.

Respiratory Protection:IF WORKPLACE EXPOSURE LIMITS ARE EXCEEDED FOR
ANY COMPONENT, A NIOSH APPROVED RESPIRATOR SUITABLE FOR COMPONENTS
LISTED IS RECOMMENDED.
Ventilation:SUFFICIENT VENT, IN VOL & PATTERN, SHOULD BE PROVIDED TO
KEEP AIR CONTAM BELOW CURRENT APPLIC OSHA PEL/ACGIH'S TLV LIM.
Protective Gloves:CHEM RESISTANT PLASTIC/RUBBER GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS &(SUPDAT)
Other Protective Equipment:ANSI APPRVD EYE WASH FOUNTAIN & DELUGE
SHOWER . APPROP IMPERVIOUS CLTHG IS REC IF PRLNG/RPTD CONT IS
LIKELY.
Work Hygienic Practices:WASH HANDS BEFORE EATING OR SMOKING.
Supplemental Safety and Health
FIRE FIGHT PROC:WATER IS USED, FOG NOZZ ARE PREF. WHEN FIGHTING FIRE
INVOLVING ALUMINUM PASTE, DO NOT USE WATER STREAM/HALOGENATED
EXTING AGENT. EXPLO HAZ:LONG DIST TO SOURCE OF IGNIT & FLASH BACK.
EY E PROT:FULL LGTH FSHLD . MATLS TOAVOID:EXTING AGENTS. ALUMINUM
(ING 16)

Boiling Pt:B.P. Text:>175F,>79C
Vapor Density:HVR/AIR
Spec Gravity:0.955
Evaporation Rate & Reference:FASTER/N-BUTYL ACETATE
Appearance and Odor:OPAQUE LIQUID; SOLVENT ODOR.
Percent Volatiles by Volume:68-85

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS. ALUMINUM FLAKE CAN REACT VIOLENTLY
W/HALOGENATED HYDROCARBONS INCL HALOGENATED FIRE (SUPP DATA)
Stability Condition to Avoid:AVOID CONTACT W/HEAT, SPARKS & OPEN FLAME.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE
CARBON DIOXIDE, CARBON MONOXIDE & UNIDENTIFIABLE ORGANIC MATERIALS.

Waste Disposal Methods:PLACE IN CLOSED CONTAINER. DISPOSE OF PRODUCT
I/A/W LOCAL, COUNTY, STATE & FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.